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The oxidation of amines with sulfonyl peroxides

โœ Scribed by Hoffman, Robert V.

Book ID
127023333
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
409 KB
Volume
98
Category
Article
ISSN
0002-7863

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The oxidation of amines with sulfonyl pe
The oxidation of amines with sulfonyl peroxides, II; Aryl rearrangement to nitrogen promoted by p-nitrobenzenesulfonyl peroxide
โœ Robert V. Hoffman; Reuben Cadena; David J. Poelker ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 253 KB

Amine oxidations exhibit a great diversity of mechanisms which depends on the oxidant, the amine type, the pH, and/or metal additives. 3 Reaction with oxidants can occur at the nitrogen lone pair by one electron or two electron oxidation or reaction can occur at the a-carbon atom by hydrogen abstra