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The oxidation of amines with sulfonyl peroxide. 8. Oxidative deamination of amines by arylsulfonyl peroxides

โœ Scribed by Hoffman, Robert V.; Kumar, Anil

Book ID
111900200
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
565 KB
Volume
49
Category
Article
ISSN
0022-3263

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The oxidation of amines with sulfonyl pe
The oxidation of amines with sulfonyl peroxides, II; Aryl rearrangement to nitrogen promoted by p-nitrobenzenesulfonyl peroxide
โœ Robert V. Hoffman; Reuben Cadena; David J. Poelker ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 253 KB

Amine oxidations exhibit a great diversity of mechanisms which depends on the oxidant, the amine type, the pH, and/or metal additives. 3 Reaction with oxidants can occur at the nitrogen lone pair by one electron or two electron oxidation or reaction can occur at the a-carbon atom by hydrogen abstra