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Oxidation of amines with bis-(diphenylphosphinyl)peroxide to give o-phosphinylated aminating reagents

โœ Scribed by Gernot Boche; Reinhard H. Sommerlade


Book ID
108372480
Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
252 KB
Volume
42
Category
Article
ISSN
0040-4020

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The oxidation of amines with sulfonyl pe
โœ Robert V. Hoffman; Reuben Cadena; David J. Poelker ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 253 KB

Amine oxidations exhibit a great diversity of mechanisms which depends on the oxidant, the amine type, the pH, and/or metal additives. 3 Reaction with oxidants can occur at the nitrogen lone pair by one electron or two electron oxidation or reaction can occur at the a-carbon atom by hydrogen abstra