✦ LIBER ✦
The oxidation of amines with sulfonyl peroxides, II; Aryl rearrangement to nitrogen promoted by p-nitrobenzenesulfonyl peroxide
✍ Scribed by Robert V. Hoffman; Reuben Cadena; David J. Poelker
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- French
- Weight
- 253 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Amine oxidations exhibit a great diversity of mechanisms which depends on the oxidant, the amine type, the pH, and/or metal additives.
3 Reaction with oxidants can occur at the nitrogen lone pair by one electron or two electron oxidation or reaction can occur at the a-carbon atom by hydrogen abstraction. A given oxidant may follow different pathways with different amines