✦ LIBER ✦

The oxidation of amines with sulfonyl peroxides. 3. Regioselectivities and substituent effects in the oxidation of benzylamines, and kinetic evidence for a two-electron pathway

✍ Scribed by Hoffman, Robert V.; Cadena, Rueben

Book ID: 127097224
Publisher: American Chemical Society
Year: 1977
Tongue: English
Weight: 868 KB
Volume: 99
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00467a017

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Three-electron oxidations. 18. Carbon-13

Three-electron oxidations. 18. Carbon-13 and deuterium isotope effects in the cooxidation of 2-hydroxy-2-methylbutyric acid and 2-propanol. Evidence for a two-step mechanism

✍ Ramesh, S.; Mahapatra, Surendra N.; Liu, Juei H.; Rocek, Jan 📂 Article 📅 1981 🏛 American Chemical Society 🌐 English ⚖ 490 KB

β-deuterium kinetic isotope effects in t

β-deuterium kinetic isotope effects in the solvolysis of 2-aryl-1,1,1-trifluoro-2-propyl tosylates and of 2-aryl-2-profyl p-nitrobenzoates. Evidence for a variation of the contribution of α-methyl substituent in stabilizing cationic reaction centers with different electron demand

✍ Kwang-Ting Liu; Yuh Wern Wu 📂 Article 📅 1986 🏛 Elsevier Science 🌐 French ⚖ 251 KB

A very high S-deuterium kinetic isotope effect, k(CH3)/k(CD3) =2.l3 at ~o'c, was found for the solvolysis of 2-(3'-chlorophenyl)-l,l,l-trifluoro-2propyl tosylate(&) and the a-CD3 analogue