𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The nucleophilic catalysed decomposition of N-methyl-N-nitroamides in aqueous buffers

✍ Scribed by Challis, Brian C.; Rosa, Eduarda; Norberto, F�tima; Iley, Jim


Book ID
118173384
Publisher
Royal Society of Chemistry
Year
1989
Tongue
English
Weight
625 KB
Volume
11
Category
Article
ISSN
1472-779X

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Kinetics and mechanism for the formation
✍ M. Niyaz Khan 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 141 KB 👁 1 views

The rate of cleavage of ethyl N-[o -(N-methyl-N-hydroxycarbamoyl)benzoyl]carbamate (ENMBC) in the buffer solutions containing N-methylhydroxylamine, acetate + Nmethylhydroxylamine, and phosphate + N-methylhydroxylamine followed an irreversible consecutive reaction path: ENMBC k 1 obs → A k 2 obs → B

Kinetics and mechanism of the decomposit
✍ J. M. Antelo; F. Arce; J. Franco; M. J. Forneas; M. E. Sanchez; A. Varela 📂 Article 📅 1986 🏛 John Wiley and Sons 🌐 English ⚖ 421 KB 👁 2 views

The decomposition reactions of N-bromodiethanolamine. N-bromoethylethanolamine, and AT-bromomethylethanolamine in aqueous solution have been studied kineticall) under various experimental conditions. The results support a proposed reaction mechanism in which the rate controlling step is assumed to b

General base catalysis in the decomposit
✍ Ll Abia; X. L. Armesto; M. Canle L.; M. V. García; M. Losada; J. A. Santaballa 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 English ⚖ 565 KB

This article analyzes the kinetics of the decomposition of N-C1-Valine in aqueous solution, which is formed rapidly by chlorination of Valine with sodium hypochlorite. A general-base catalyzed process not yet described is reported. The experimental evidence shows two competitive decomposition paths:

Kinetics and mechanism of the decomposit
✍ William D. Stanbro; Michael J. Lenkevich 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 English ⚖ 356 KB 👁 2 views

Aqueous bromine reacts with alkyl-sidechain a-amino acids through a series of steps resulting in the formation of the corresponding alkyl aldelydes and nitriles. The kinetics and the mechanism of the interaction of bromine with alanine are examined. The products and the rates of this reaction are de