Aqueous bromine reacts with alkyl-sidechain a-amino acids through a series of steps resulting in the formation of the corresponding alkyl aldelydes and nitriles. The kinetics and the mechanism of the interaction of bromine with alanine are examined. The products and the rates of this reaction are de
Kinetics and mechanism of the decomposition of N-bromoalcoholamines in aqueous solution
β Scribed by J. M. Antelo; F. Arce; J. Franco; M. J. Forneas; M. E. Sanchez; A. Varela
- Publisher
- John Wiley and Sons
- Year
- 1986
- Tongue
- English
- Weight
- 421 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0538-8066
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β¦ Synopsis
The decomposition reactions of N-bromodiethanolamine. N-bromoethylethanolamine, and AT-bromomethylethanolamine in aqueous solution have been studied kineticall) under various experimental conditions. The results support a proposed reaction mechanism in which the rate controlling step is assumed to be the formation ofan imine which is then hydrolyzed to the final decomposition products.
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