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The kinetics and mechanism of the decomposition of N-chloroleucine

✍ Scribed by Juan M. Antelo; Florencio Arce; Julia Franco; Pilar Rodriguez; Angel Varela


Publisher
John Wiley and Sons
Year
1988
Tongue
English
Weight
334 KB
Volume
20
Category
Article
ISSN
0538-8066

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✦ Synopsis


At 298 K the rate constant for the decomposition of N-chloroleucine has the constant value 3.20 >: lo-* s-' over the range pH 5-12, increases with increasing acidity at pH < 5, and increases with pH a t pH > 12. A mechanism is put forward which explains these results.


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