The decomposition reactions of N-bromodiethanolamine. N-bromoethylethanolamine, and AT-bromomethylethanolamine in aqueous solution have been studied kineticall) under various experimental conditions. The results support a proposed reaction mechanism in which the rate controlling step is assumed to b
The kinetics and mechanism of the decomposition of N-chloroleucine
β Scribed by Juan M. Antelo; Florencio Arce; Julia Franco; Pilar Rodriguez; Angel Varela
- Publisher
- John Wiley and Sons
- Year
- 1988
- Tongue
- English
- Weight
- 334 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0538-8066
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β¦ Synopsis
At 298 K the rate constant for the decomposition of N-chloroleucine has the constant value 3.20 >: lo-* s-' over the range pH 5-12, increases with increasing acidity at pH < 5, and increases with pH a t pH > 12. A mechanism is put forward which explains these results.
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