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Kinetics and mechanism for the formation of o-carboxy(N-methyl)-benzohydroxamic acid in the cleavage of ethyl N-[o-(N-methyl-N-hydroxycarbamoyl)-benzoyl]carbamate in N-methylhydroxylamine, acetate, and phosphate buffers

✍ Scribed by M. Niyaz Khan

Publisher: John Wiley and Sons
Year: 2003
Tongue: English
Weight: 141 KB
Volume: 35
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.10142

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✦ Synopsis

The rate of cleavage of ethyl N-[o -(N-methyl-N-hydroxycarbamoyl)benzoyl]carbamate (ENMBC) in the buffer solutions containing N-methylhydroxylamine, acetate + Nmethylhydroxylamine, and phosphate + N-methylhydroxylamine followed an irreversible consecutive reaction path: ENMBC k 1 obs → A k 2 obs → B where A and B represent N-hydroxyl group cyclized product of ENMBC and o -(N-methyl-N-hydroxycarbamoyl)benzoic acid, respectively.

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