๐”– Bobbio Scriptorium
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The mechanism of the rearrangement of p-quinamines to 4-aminodiphenylethers an analogue of the benzidine rearrangement

โœ Scribed by B. Miller


Publisher
Elsevier Science
Year
1962
Tongue
French
Weight
199 KB
Volume
3
Category
Article
ISSN
0040-4039

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The mechanism of the thermal conversion of allyltrimethylsilane to trimethylvinylsilane does not involve methylene extrusion.

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The rearrangement of Z(vinyloxy)alkyl to 4-ketobutyl radicals has been demonstrated b proceed by a two step mechanism involving initial 5-endo-trigoual cyclii 10 give a tetrahydrof~yl radical which thtn fragments to the final radical. Fragmentation of the tetrahydrofrwnyl radicals is demonstrated by