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Mechanism of the benzidine rearrangement

โœ Scribed by M.J.S. Dewar; Hilary McNicoll

Publisher
Elsevier Science
Year
1959
Tongue
French
Weight
90 KB
Volume
1
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

HANMOD md SHIRE ' 8howed come yearr ego that the bensidine rearrangement 18 of seoond order with re8peot to the aoid oatalyat; they therefore ' G. S.

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THE rate of rearrangement of m-hydrazoaniline to g,2'-diaminobenzidine is inversely proportional to the concentration of strong acid in 95 per cent alcoholic solutions over the range of acidities 0.0067-0.04 M. The result Publications, London (1958).

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Anionic micelles accelerate specific hydrogen ion catalyzed reactions, but to date most information relates to hydrolyses. l-3 We find a very large rate enhancement of the benzidlne rearrangement of 1,2-diphenyl bydrazme (I) by anionic micelles of sodium lauryl sulfate (NaIS)!