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The mechanism of the benzidine rearrangement - IV evidence for a metastable intermediate

✍ Scribed by George S. Hammond; James S. Clovis

Publisher
Elsevier Science
Year
1962
Tongue
French
Weight
236 KB
Volume
3
Category
Article
ISSN
0040-4039

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✦ Synopsis

THE rate of rearrangement of m-hydrazoaniline to g,2'-diaminobenzidine is inversely proportional to the concentration of strong acid in 95 per cent alcoholic solutions over the range of acidities 0.0067-0.04 M. The result Publications, London (1958).

πŸ“œ SIMILAR VOLUMES

The Cyclopropylcarbinyl-Cyclobutyl-Homoa
The Cyclopropylcarbinyl-Cyclobutyl-Homoallylic Rearrangement. Part III. Evidence for a symmetrical intermediate and for two discrete rearrangement processes
✍ Manfred Geisel; Cyril A. Grob; RenΓ© P. Traber; Werner Tschudi πŸ“‚ Article πŸ“… 1976 πŸ› John Wiley and Sons 🌐 German βš– 879 KB

## Abstract In buffered 70% aqueous dioxane the cyclopropylcarbinyl (**1**‐X), __endo__‐cyclobutyl (**2**‐X) and homoallylic (**3**‐X) derivatives (X = nucleofuge) react to give the same mixture of alcohols **1**‐OH and **3**‐OH by way of a common intermediate, the symmetrical homoallylic ion **22*