Evidence for a stepwise mechanism for the γ-hydrogen rearrangement
✍ Scribed by James S. Smith; D F. W. McLafferty
- Publisher
- John Wiley and Sons
- Year
- 1971
- Tongue
- English
- Weight
- 200 KB
- Volume
- 5
- Category
- Article
- ISSN
- 1076-5174
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📜 SIMILAR VOLUMES
The mechanism of the McLafferty rearrangement of the butanal radical cation to ethylene and vinyl alcohol cation is found, by ab initio calculations, to be stepwise. The results of a previous ab initio study are inconclusive because of symmetry restriction in their geometry optimization. Although t
## Abstract In buffered 70% aqueous dioxane the cyclopropylcarbinyl (**1**‐X), __endo__‐cyclobutyl (**2**‐X) and homoallylic (**3**‐X) derivatives (X = nucleofuge) react to give the same mixture of alcohols **1**‐OH and **3**‐OH by way of a common intermediate, the symmetrical homoallylic ion **22*