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Evidence for a carbene intermediate in the thermal rearrangement of a cyclopropene

✍ Scribed by Richard D. Streeper; P.D. Gardner

Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
138 KB
Volume
14
Category
Article
ISSN
0040-4039

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## Abstract In buffered 70% aqueous dioxane the cyclopropylcarbinyl (**1**‐X), __endo__‐cyclobutyl (**2**‐X) and homoallylic (**3**‐X) derivatives (X = nucleofuge) react to give the same mixture of alcohols **1**‐OH and **3**‐OH by way of a common intermediate, the symmetrical homoallylic ion **22*