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Evidence for Intermediates in the Cycloaddition of Singlet Carbenes

✍ Scribed by Prof. Dr. Bernd Giese; Dr. Woo-Bung Lee; Carola Neumann

Publisher
John Wiley and Sons
Year
1982
Tongue
English
Weight
125 KB
Volume
21
Category
Article
ISSN
0044-8249

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## Abstract The photochemistry of 2,6‐dimethyl‐4‐chlorophenol (**6**) has been studied in methanol and trifluoroethanol (TFE) through product studies and transient absorption spectroscopy. Chloride loss from triplet **6** gave triplet hydroxyphenyl cation **14**, which equilibrated with triplet oxo