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Copper(I) Carbenes: The Synthesis of Active Intermediates in Copper-Catalyzed Cyclopropanation

✍ Scribed by Bernd F. Straub; Peter Hofmann


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
95 KB
Volume
113
Category
Article
ISSN
0044-8249

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The mechanism of copper(I)-catalyzed olefin cyclopropanation with diazomethanes has been studied at the BP86/AE1 level of density-functional theory. For the model system Cu(diazabutadiene) + + ethene + diazomethane, copper carbene complexes are confirmed as viable intermediates, with rate-determinin