HANMOD md SHIRE ' 8howed come yearr ego that the bensidine rearrangement 18 of seoond order with re8peot to the aoid oatalyat; they therefore ' G. S.
Micellar catalysis of the benzidine rearrangement
โ Scribed by C.A. Bunton; R.J. Rubin
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- French
- Weight
- 185 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
โฆ Synopsis
Anionic micelles accelerate specific hydrogen ion catalyzed reactions, but to date most information relates to hydrolyses. l-3 We find a very large rate enhancement of the benzidlne rearrangement of 1,2-diphenyl bydrazme (I) by anionic micelles of sodium lauryl sulfate (NaIS)!
๐ SIMILAR VOLUMES
College, THREE cases of rearrangement of hydrazobenzenes have been reported in recent years in which the order with respect to acid was between first and second. These-are o-hydrazotoluene\* (1.6), 4-methyl-and 4-t-butyl-4'-chlorohydrazobenzene3 (1.58 and 1.51). The last two results were attributed