On the mechanism of the allylsilane-to-vinylsilane rearrangement
โ Scribed by Susan M. Neider; Gregory R. Chambers; Maitland Jones Jr.
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- French
- Weight
- 156 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
The mechanism of the thermal conversion of allyltrimethylsilane to trimethylvinylsilane does not involve methylene extrusion.
๐ SIMILAR VOLUMES
The shock-induced thermal decompositions of vinylsilane and vinylsilane-d, (0.2% on argon) have been studied in the temperature range of 1085-1275 K, and at total pressures of about 3100 tom. In systems without silylene traps, some induced decomposition occurs which is attributed to the silylene cha
The Claisen rearrangement of N-BOC-glycinate esters 1a-1d led to the formation of a-allylsilane-functionalized amino acids 2-3 in good yield (up to 80%). The diastereoselectivity of the reaction varied from 2:1 to 29:1 (syn:anti ) for 1a depending on reaction conditions. In the case of the Ireland-C