Mechanism of the Rearrangement of 7-Vinylnorcaradienes. -Thermal rearrangement of the diastereomeric 7-vinylnorcaradienes (I) and (II) provides three products, two formed via a 1,3-and 3,5-vinylcyclopropanecyclopentane rearrangement and the third one resulting from a 3,3-cope rearrangement.
โฆ LIBER โฆ
On the mechanism of the rearrangement of 7-vinylnorcaradienes
โ Scribed by Shigeo Kohmoto; Naohiro Nakayama; Jun-ichi Takami; Keiki Kishikawa; Makoto Yamamoto; Kazutoshi Yamada
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- French
- Weight
- 263 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0040-4039
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Tropones substituted in the ~-position by good leaving groups are converted into benzoic acid derivatives by a wide variety of bases; when two leaving groups are available, a mixture of products is often obtained (3).