𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The mechanism of the direct photo-oxidative decarboxylation of α-oxo-carboxylic esters

✍ Scribed by R. Stephen Davidson; Dean Goodwin; Julie E. Pratt


Book ID
108372758
Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
502 KB
Volume
39
Category
Article
ISSN
0040-4020

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


The direct photo-oxidative decarboxylati
✍ R. Stephen Davidson; Dean Goodwin; Geoffrey Turnock 📂 Article 📅 1980 🏛 Elsevier Science 🌐 French ⚖ 225 KB

a-Oxo-carboxylic acids undergo photo-oxidative decarboxylation from both C-l and C-2 positions, and reaction does not involve singlet oxygen: a mechanism involving an electron transfer reaction is postulated.

The stereochemical course of anionic dec
✍ E.J. Corey; Thomas H. Lowry 📂 Article 📅 1965 🏛 Elsevier Science 🌐 French ⚖ 265 KB

Ol-Sulfony' carbanions of structure R-SO,-T (Rl)(R2) ACIDS Mass. 02138 can be generated from optically active precursors R-S02-C (Rl)(R2)(Y) in hydroxylic media and protonated to give optically active products, R-S02-CH(Rl)(R2), with high stereospecificity. This remarkable