Oxidative decarboxylation of α-keto carb
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Wataru Ando; Hajime Miyazaki; Takeshi Akasaka
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Article
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1982
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Elsevier Science
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French
⚖ 194 KB
Photosensitized oxygenation of a-keto carboxylic acids in the presence of diazo compounds afforded the corresponding carboxylic acids and carbon dioxide in high yields; oxidative decarboxylation by carbonyl oxides occurred. Hydroxylations catalyzed by several dioxygenases require cc-keto carboxylic