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The mechanism of the aluminium bromide catalyzed isomerization of n-propyl bromide

✍ Scribed by H. S. A. Douwes; E. C. Kooyman

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
467 KB
Volume
83
Category
Article
ISSN
0165-0513

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πŸ“œ SIMILAR VOLUMES

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When cuprous bromide reacts with an excess of ethylmagnesium bromide in ethyl or c-butyl ether, a copper-containing red solution is formed that markedly catalyzes the reaction of ethyl bromide with ethylmagnesium bromide to give a mixture of ethane and ethylene, 2 usually in the ratio of 1.3 or less

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## Abstract Spectrophotometric titration curves of β‐phenylethyl bromide and aluminium bromide at βˆ’80Β° in carbon disulphide and heptane at 430 and 250 mΞΌ respectively show the formation of a 1 : 1 complex by a fast reaction, which goes to completion.