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The catalyzed reaction of alkyl bromides with alkylmagnesium bromides

✍ Scribed by V.D. Parker; C.R. Noller

Publisher
Elsevier Science
Year
1963
Tongue
French
Weight
214 KB
Volume
4
Category
Article
ISSN
0040-4039

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✦ Synopsis

When cuprous bromide reacts with an excess of ethylmagnesium bromide in ethyl or c-butyl ether, a copper-containing red solution is formed that markedly catalyzes the reaction of ethyl bromide with ethylmagnesium bromide to give a mixture of ethane and ethylene, 2 usually in the ratio of 1.3 or less. This red solution, the nature of which is uncertain, is hereafter simply called the catalyst. Recent work' has shown, 1 American Chemical 2 C. B. Linn and C. (1936). 3 (a) H. Cerfontani (1958); (b) J. C.

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