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Chemical reaction dynamics of barium atom with alkyl bromides

✍ Scribed by Keli Han; Xiguang Zheng; Benfan Sun; Guozhong He; Ruiqin Zhang


Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
422 KB
Volume
181
Category
Article
ISSN
0009-2614

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✦ Synopsis


Laser-induced fluorescence (LIF) has been used to probe the internal energy state of nascent BaBr products formed in the reactions of Bat BrR ( R=CZHS, C H C H 3 7, 4 P, CsH,, ). Moreover, these reactions have been theoretically studied in an LEPS potential energy surface with a single-particle approximation for the R group. The theoretical results are in good agreement with the experimental ones.


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Differential reaction cross sections have been masured as a function of inithl trantitional enegy for the 1 afom abstraction reactions of Cl atoms with CII,l. CZHsI, C,H,I molecules. At lower initial transhtiorul energy. long-lived collision dynamics are observed which persist at hgher initial trans