## Abstract The reaction of 2,4,6‐trichloropyrimidine 1 with a variety of 4‐substituted anilines 2 has been investigated. Monosubstitution occurs readily for all anilines except those containing strongly electron‐withdrawing groups. The yields of the isomeric products 3 and 4 parallel the Hammet co
✦ LIBER ✦
The reaction of allyldialkyltelluronium bromides with anilines
✍ Scribed by Caiding Xu; Shoumao Lu; Xian Huang
- Publisher
- John Wiley and Sons
- Year
- 1994
- Tongue
- English
- Weight
- 148 KB
- Volume
- 5
- Category
- Article
- ISSN
- 1042-7163
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✦ Synopsis
Abstract
Allyldialkyltelluronium bromides were treated with aromatic amines in 1,2‐dichloroethane, readily giving allyl aryl amines in excellent yields.
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## Abstract At bromide concentrations higher than 0.1 M, a second term must be added to the classical rate law of the bromate–bromide reaction that becomes −d[BrO~3~^−^]/d__t__ = [BrO~3~^−^][H^+^]^2^(__k__~1~[Br^−^] + __k__~2~[Br^−^]^2^). In perchloric solutions at 25°C, __k__~1~ = 2.18 dm^3^ mol^−