The kinetics of the aluminium bromide catalyzed isomerization of 1-propyl bromide II
β Scribed by H.S.A. Douwes
- Publisher
- Elsevier Science
- Year
- 2007
- Tongue
- English
- Weight
- 196 KB
- Volume
- 272
- Category
- Article
- ISSN
- 1381-1169
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π SIMILAR VOLUMES
The Chemistry.of reaction systems in which propargyl and allenic radicals are formed as resonance hybrids has generally indicated that the propargyl radical makes the greater contribution, in that the products are usually related to the propargyl structure. -CEC-CC " -e=c=c< Caserio and Pratt (1) h
## Abstract At bromide concentrations higher than 0.1 M, a second term must be added to the classical rate law of the bromateβbromide reaction that becomes βd[BrO~3~^β^]/d__t__ = [BrO~3~^β^][H^+^]^2^(__k__~1~[Br^β^] + __k__~2~[Br^β^]^2^). In perchloric solutions at 25Β°C, __k__~1~ = 2.18 dm^3^ mol^β