The mechanism of reaction of nitrosyl with met- and oxymyoglobin: an ESR study
โ Scribed by Ladislau Martin Neto; Otaciro R. Nascimento; Marcel Tabak; Ignez Caracelli
- Book ID
- 113267075
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 684 KB
- Volume
- 956
- Category
- Article
- ISSN
- 0167-4838
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Photolytically generated tert-butoxyl radicals react with vinyl-and propenyl ethers by hydrogen abstraction and addition to the double bond; the abstraction/addition ratio and the regioselectivity of addition are interpreted in terms of predominant steric interactions.
During the parallel (2 + 2)-and (4 + 2)-cycloaddition reactions of aromatic thiones such as xanthene-9-thione with substituted allenes XCH=C==CH, (X = OR, SR, NMe,, Ph), a strong ESR signal is observed. This signal is associated with the (4 + 2)-cycloaddition reaction, affording thiopyran derivative