ESR and UV study of an electron transfer reaction
β Scribed by R. Chang; J.Hodge Markgraf
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 95 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
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ESR studies using molybdenum enriched in g5hIo have confirmed that tOas is stabilised at hio6\* sites at 77 K on silica and alumina supported molybdenum. Warming the MolAlzO3 to 300 ); leads to an incre-ase in the number of (O&ions observed due to electron transfer from seduced molybdenum sites to g
The exchange between durosemiquinone triplet-ions (DQ; ,2Na+) and the parent quinone in THF was studied. Both sodium ions are transferred in the process, and ihe ESR spectrum in the presence of 2M duroquinone collapses into '/ lines. The sodium coupling constant in this spectrum is 1.93 MHz whereas