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Reaction of vinyl- and propenyl-ethers with tert-butoxyl radicals - an ESR study

✍ Scribed by Hans-Gert Korth; Reiner Sustmann

Book ID
104228986
Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
220 KB
Volume
26
Category
Article
ISSN
0040-4039

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✦ Synopsis

Photolytically generated tert-butoxyl radicals react with vinyl-and propenyl ethers by hydrogen abstraction and addition to the double bond; the abstraction/addition ratio and the regioselectivity of addition are interpreted in terms of predominant steric interactions.

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