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The mechanism of anodic dealkylation of aliphatic amines in acetonitrile

✍ Scribed by Sidney D. Ross

Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
164 KB
Volume
14
Category
Article
ISSN
0040-4039

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✦ Synopsis

In acetonitrile containing water aliphatic amines are smoothly dealkylated electrochemically at platinum to give an amine of lower order and an aldehyde. When the oxidation of either tri-n-propylamine or di-n-propylamine was carried out in rigorously dried acetonitrile containing concentration five times greater than the initial amine hyde obtained was a-deuteriopropionaldehyde. Mann1 has mechanism,(l) -(4), for this reaction.

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