๐”– Bobbio Scriptorium
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The electrochemical oxidation of some aliphatic hydrocarbons in acetonitrile

โœ Scribed by M. Fleischmann; D. Pletcher


Publisher
Elsevier Science
Year
1968
Tongue
French
Weight
159 KB
Volume
9
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES


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This note reports on the electrochemical oxidation in acetonitrile of bis-(phenylthio)-methane, a biphenyl mercaptal. In the presence of either sodium or tetraethylammonium perchlorate this compound is cleanly oxidized to diphenyldisulfide and formaldehyde at a platinum electrode. This result is uni

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Previous papers t' 2 have reported the partial anodic oxidation of aliphatic hydrocarbons at room temperature at a smooth platinum electrode in acetonitrile containing tetraethylammonium tetrafluoroborate as the base electrolyte. A detailed investigation of the oxidation of propylene 2 has shown tha