The magnetic circular dichroism of the 1Σ+→1Δ transition in carbonyl sulfide
✍ Scribed by Aharon Gedanken; Itamar Burak
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 208 KB
- Volume
- 137
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
The magnetic circular dichroism spectrum of the 'Z + + 'A transition in OCS contains two signals of opposite sign. The spectrum is interpreted as resulting from two B terms associated with the 'A' and 'A" states that originate from the 'A state, which undergoes a change in its geometry to a bent conformation.
📜 SIMILAR VOLUMES
MCD measuremepts have been used to estimate the ground-and excited-state magnetic moments and zero-field splittings for the 4A2 -'E('D) km&ion in CssCoCls. Most of the recenrextensive work on magnetic circular dichroism (MCD) [l] has concentrated on situations in which the linewidths have been large
Emission spectra of the 0-0 bands of the a IA -~ X 3~.-transitions of PH and PD have been observed in the near-infrared spectral region near 1.33 Ixm. The phosphorus hydride radicals were generated and excited in a fast-flow system by the reaction of phosphorus vapor with hydrogen or deuterium atoms
The MCD (magnetic circular dichroism) of CHsI, CHsBr and CHaCl has been studied in the spectral region of the n --L of continuum (3500-1700 4). The MC0 spectrum ofCH3I makes it possib!e to resoive the three excited states contributing to the continuum. The peak energies and the oscillator strengths