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Magnetic circular dichroism of the 4A2 → 2E(2D) transition in Cs3CoCl5

✍ Scribed by J.C. Collingwood; P. Day; R.G. Denning

Publisher
Elsevier Science
Year
1971
Tongue
English
Weight
229 KB
Volume
10
Category
Article
ISSN
0009-2614

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✦ Synopsis

MCD measuremepts have been used to estimate the ground-and excited-state magnetic moments and zero-field splittings for the 4A2 -'E('D) km&ion in CssCoCls. Most of the recenrextensive work on magnetic circular dichroism (MCD) [l] has concentrated on situations in which the linewidths have been large corn-* pared to both the Zeeman splitting and kT. The widely used formalism of Buckingham and Stephens [2] contains approximations which are only valid under these conditions. When measurements are made on single crystals at 4.2'K and fields of about 50 kG it may be

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