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Interaction of the 2E(D) state of Co2+ with a jahn-teller active mode in [N(CH3)4]2CoCl4

✍ Scribed by R. Laiho; A. Treshchalov

Publisher: Elsevier Science
Year: 1981
Tongue: English
Weight: 319 KB
Volume: 80
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(81)85081-6

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✦ Synopsis

The transition 4Aa + a E of Co'+ has been investigated m [N(CH& JaCoC4 using optical absorption and magnetrc circular dichroism. Three groups of lines wrth 774 cmml progressions were observed. The structure of the spectra indrcates a J-T interaction in the 'El state with strong depression of tile frequency of the J-T active mode. The ground-state splitting 1s7_2cm-I.

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