✍ Scribed by Yoshifumi Kato; Isamu Nakano
No coin nor oath required. For personal study only.
The magnetic circular dichrokm (MCD) for the three low-energy absorption bands of the Eu(C2H$!i04)3 -VH20 crystal has been measured at room temperature. It may$e well understood from the MCD as well as from other experimental results that two of these bands, 7F1 + Do and 7Fo -+ D1, are of magnetic dipole origin. However, the MCD of another baud at about 18650 cm-', 'F1 + 'D1, cannot be interpreted as being only one electric dipole in origin, which has been pointed out by several investigations. The present MCD analysis indicates that although this broad band consists of one electric-and two magnetic-clipole transitions, each of which has a sizeable absorption strength, the MCD spectrum originates exclusively from the two magnetic dipole transitions.
📜 SIMILAR VOLUMES
One of the most rapidly expanding areas of coordination chemistry research is the design of magnetic materials based on molecular building blocks. [1] A perusal of the literature reveals that a successful design strategy for preparing molecular magnets is the coordination of organic radicals such as
The encrg~cs of EPR transitions of of field at low fields. The + :, +f and IGoGd3+ in LzI(C~H~SO~)~~ 9D20 at 77.2 K arc obscrvcd to bc nonlmoar functmns -z, -i transition cncrgics convcrgc ~symmctrically below 10 G and differ by only = 3 hIi at the lowest fields employed.