One of the most rapidly expanding areas of coordination chemistry research is the design of magnetic materials based on molecular building blocks. [1] A perusal of the literature reveals that a successful design strategy for preparing molecular magnets is the coordination of organic radicals such as
A Rare-Earth Metal TCNQ Magnet: Synthesis, Structure, and Magnetic Properties of {[Gd2(TCNQ)5(H2O)9][Gd(TCNQ)4(H2O)3]}⋅4 H2O
✍ Scribed by Hanhua Zhao; Mervin J. Bazile; Jr.; José R. Galán-Mascarós; Kim R. Dunbar
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 253 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0044-8249
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Single crystals of Lu(ClO 4 ) 3 ´3 H 2 O were obtained by slow dehydration of Lu(ClO 4 ) 3 ´6 H 2 O at 140 °C under flowing argon. The compound crystallizes in the triclinic crystal system (P1, Z = 2, a = 750.3(1), b = 838.4(1), c = 1054.6(2) pm, a = 79.77(2)°, b = 79.18(2), c = 63.83(2), R all = 0.
The synthesis and characterization of transition-metal coordi-oxygen atoms of the four organic ligands. The non-participation of the pyridine nitrogen atom is unusual. The two water nation compounds containing the ligand diethyl 2-quinolylmethylphosphonate (2-qmpe) is described. Complexes of molecul