The kinetics of the photochlorination of perfluoro-2-butene under intermittent light
✍ Scribed by M.C. Gonzalez; E. Castellano
- Publisher
- Elsevier Science
- Year
- 1982
- Weight
- 405 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0047-2670
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The kinetics of the gas phase elimination of 2-bromo-2-butene were determined in a static system over the temperature range of 340-380°C and pressure range of 37-134 torr. The reaction in seasoned vessels, even in the presence of a free radical inhibitor, is catalyzed by hydrogen bromide. Under maxi
## Abstract We have employed the laser flash photolysis–resonance fluorescence technique to investigate the gas‐phase kinetics of elementary steps in the Br‐initiated oxidation of 2,3‐dimethyl‐2‐butene (TME) under atmospheric conditions. At __T__⩾ 274 K, measured rate coefficients are independent o