𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Kinetics and mechanism of the permanganate oxidation of cis-2-butene-1,4-diol

✍ Scribed by Nguyen Thanh Son; Miklós Jáky; LászlóI. Simándi


Publisher
Elsevier Science
Year
1976
Weight
224 KB
Volume
12
Category
Article
ISSN
0020-1650

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Kinetics and mechanism of oxidation of 1
✍ Rafeek G. Panari; Abdulazizkhan L. Harihar; Sharanappa T. Nandibewoor 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 79 KB 👁 2 views

The kinetics of the oxidation of 1,10-phenanthroline (1,10-phen) by permanganate were investigated in alkaline medium. A first-order, fractional-order and zero-order dependence of the rate each in [MnO 4 À ], [1,10-phen] and [OH À ], respectively, was observed. The data suggest that the oxidation pr

Kinetics and mechanism of the oxidation
✍ Miklós Jáky; János Szammer; Edit Simon-Trompler 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 131 KB 👁 2 views

## Abstract The kinetics and mechanism of permanganate ion oxidation of acetylacetone (Acac) was studied in acidic and alkaline media. The rate constants for keto, enol, and enolate anions were determined and discussed. Delocalization of the π‐electrons of the double bond by conjugation results in

Mechanism and kinetics of hypophosphite
✍ K. Wojciechowski; A. Malecki 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 154 KB 👁 2 views

The kinetics of the permanganate-hypophosphite redox reaction has been studied over a wide range of pH by using a stopped-flow technique. It has been found that the reaction leads to the formation of phosphite and orthophosphate, and that the molar ratio of the final products depends on pH. The prop

Permanganate ion oxidations X. Kinetics
✍ Fillmore Freeman; Dorrece Lynn Bond; Steven Martin Chernow; Pamela Ann Davidson; 📂 Article 📅 1978 🏛 John Wiley and Sons 🌐 English ⚖ 463 KB 👁 1 views

## Abstract Permanganate ion rapidly oxidizes the thiol group in 2‐thiouracils (2,3‐dihydro‐2‐thioxo‐4(1H)‐pyrimidinones, 4‐hydroxy‐2‐pyrimidinethiols) to the corresponding uracil‐2‐sulfonates in phosphate‐buffered solutions. The oxidations, which are first order in oxidant and first order in reduc

Kinetics and mechanisms of the oxidation
✍ M. J. Insausti; F. Mata-Perez; M. P. Alvarez-Macho 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 English ⚖ 516 KB

The oxidation of L-Phenylalanine by permanganate ion in aqueous phosphate buffers is autocatalized by the inorganic reaction product, which is stabilized in solution by adsorption of phosphate ions on its surface. This product is a soluble form of colloidal manganese dioxide. The rate of the noncata