Kinetics and mechanism of the gas phase photochlorination of 1,2-dichloro-1,2-difluoroethylene
โ Scribed by H.E. Di Loreto; E. Castellano
- Publisher
- Elsevier Science
- Year
- 1987
- Weight
- 578 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0047-2670
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The rate constant for the combination of 2,2-dichloro-l,1 ,I-trifluoroethyl radicals has been measured by applying the rotating sector technique to the gas phase photochlorination of 2,2-dichloro-l,l,l-trifluoroethane at 315ยฐK. The observed value is 6.89 X 10' 2 cc/rnole .set. This value is in excel
The gas phase pyrolysis of 1,1,1,2-tetrachloropropane was studied in a ,static system and seasoned vessel over the temperature range of 393.0-452.8"C and pressure range of 27.5-1 18.5 torr. The reaction is homogeneous, unimolecular, follows a first-order rate law, and is not affected by the presence