The kinetics of the gas phase reaction between NOz and CFzCCIz has been investigated in the temperature range from 50 to 80ยฐC. The reaction is homogeneous. Three prod- and equimolecular amounts of ClNO and of OZNCFZC(O)CI. The rate of consumption of the reactants is independent of the total pressur
The kinetics of the photochemical reaction between trifluoromethylhypochlorite (CF3OCl) and 1,1-dichloro-2,2-difluoroethylene (CF2CCl2)
โ Scribed by Lelia Dicelio; H.J. Schumacher
- Publisher
- Elsevier Science
- Year
- 1979
- Weight
- 460 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0047-2670
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๐ SIMILAR VOLUMES
The thermal addition of CF,0sCF3(T 1 to CF2CCl2(E) has been investigated between 49.6 and 69.5"C. The initial pressure of CFJ03CF3 was varied between 7 and 240 torr and that of CF2CC12 between 4 and 600 torr. Four products of formula CF30(E),00CF3, wherej = 1 + 4 are formed. The sum of the products
The kinetics of four gas-phase reactions involving halogenated methyl radicals (R,==CF,, CF2C1, CFCI,, and eel,) with molecular chlorine have been studied using a tuhular reactor coupled to a photoionization mass spectrometer. The radicals were homogeneously generated by the pulsed photolysis of pre
## Abstract Rate constants were determined for the reactions of OH radicals with the hydrofluoroethers (HFEs) CH~2~FCF~2~OCHF~2~(__k__~1~), CHF~2~CF~2~OCH~2~CF~3~ (__k__~2~), CF~3~CHFCF~2~OCH~2~CF~3~(__k__~3~), and CF~3~CHFCF~2~OCH~2~CF~2~CHF~2~(__k__~4~) by using a relative rate method. OH radical