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The kinetics of successive addition of oxirane to alkanethiols in the presence of basic catalysts

✍ Scribed by Jan Chlebicki; Zbigniew Cichacz

Publisher: John Wiley and Sons
Year: 1989
Tongue: English
Weight: 414 KB
Volume: 21
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550210103

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✦ Synopsis

Rate constants and activation parameters of direct reaction of oxirane with certain alkyl-2-hydroxyethyl sulfides and/or successive oxyethylene adducts in the presence of basic catalysts were studied at temperatures 323-353 K. The reactions were found to be of the first order with respect to oxirane, sulfide, and catalyst concentrations. The kinetics are consistent with a termolecular mechanism.

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