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The kinetics of successive addition of methyloxirane or ethyloxirane to alkanethiols in the presence of basic catalysts

✍ Scribed by Jan Chlebicki; Zbigniew Cichacz

Publisher
John Wiley and Sons
Year
1990
Tongue
English
Weight
432 KB
Volume
22
Category
Article
ISSN
0538-8066

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✦ Synopsis

Rate constants and activation parameters for the direct addition reaction of methyloxirane or ethyloxirane to alkyl-2-hydroxyalkyl sulfides or successive oxypropylene and oxybutylene adducts in the presence of basic catalysts were determined at 373-403 K. This reaction was found to be of the first order with respect to alkyloxirane, sulfide, and catalyst.

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