Rate constants for the reactions of oxirane with alkanethiols in the presence of basic catalyst were studied at the temperature range of 20-50°C. A mechanism of these reactions has been proposed and appropriate kinetic equatlon has been presented.
The kinetics of propylene oxide reaction with certain alkylamino alcohols in the presence of basic catalysts
✍ Scribed by Kazimiera Ślipko; Jan Chlebicki
- Publisher
- John Wiley and Sons
- Year
- 1981
- Tongue
- English
- Weight
- 305 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0538-8066
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✦ Synopsis
Abstract
Rate constants for direct reactions of propylene oxide with certain aminoisopropanols in the presence of basic catalysts were studied at a temperature of 363–383 K. This reaction was found to be of the first order in propylene oxide, amino alcohol and catalyst. The observed kinetics are consistent with a termolecular mechanism.
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