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The kinetics of oxiranes addition to bis/2-hydroxyalkyl/disulfides and bis/2-hydroxyalkyl/sulfides in the presence of N,N-dimethylcyclohexylamine

✍ Scribed by Kazimiera A. Wilk; Adam Sokołowski; Bogdan Burczyk; Jan Chlebicki

Publisher: John Wiley and Sons
Year: 1987
Tongue: English
Weight: 450 KB
Volume: 19
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550190704

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✦ Synopsis

Rate constants for the reaction of oxiranes with bis/2-hydroxyalkyl/disulfides, bis/2-hydroxyalkyllsulfides, and 1,6-hexanediol in the presence of N,N-dimethylcyclohexylamine were studied at the temperature range of 50-90°C. A mechanism of these reactions has been proposed and its kinetic equation has been presented.

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