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The intramolecular silyl-modified Sakurai (ISMS) reaction. A simple and versatile synthesis of tetrahydropyrans, spiro ethers, and spiro ketals

✍ Scribed by Marko, Istvan E.; Mekhalfia, Abdelaziz; Bayston, Daniel J.; Adams, Harry


Book ID
115486769
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
390 KB
Volume
57
Category
Article
ISSN
0022-3263

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The intramolecular silyl modified sakura
✍ Abdelaziz Mekhalfia; István E Markó; Harry Adams 📂 Article 📅 1991 🏛 Elsevier Science 🌐 French ⚖ 248 KB

By employing the intramolecular version of the SMS reaction, oxocenes, including spiroethers and spiroketals, can be prepared in a highly convergent, one-step operation. In the preceding communicationl, we have described our initial findings on a novel and powerful methodology -The Silyl Modified S