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The Intramolecular Silyl-Modified Sakurai (ISMS) reaction. Stereoselective preparation of tri-and tetra-substituted tetrahydropyrans.

✍ Scribed by István E Markó; Daniel J Bayston


Publisher
Elsevier Science
Year
1993
Tongue
French
Weight
223 KB
Volume
34
Category
Article
ISSN
0040-4039

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The intramolecular silyl modified sakura
✍ Abdelaziz Mekhalfia; István E Markó; Harry Adams 📂 Article 📅 1991 🏛 Elsevier Science 🌐 French ⚖ 248 KB

By employing the intramolecular version of the SMS reaction, oxocenes, including spiroethers and spiroketals, can be prepared in a highly convergent, one-step operation. In the preceding communicationl, we have described our initial findings on a novel and powerful methodology -The Silyl Modified S