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The influence of the lattice on the spin transition in solids. Investigations of the high spin ag low spin transition in mixed crystals of [FexM1−x(2−pic)3]C12·MeOH

✍ Scribed by P. Adler; L. Wiehl; E. Meibner; C.P. Köhler; H. Spiering; P. Gütlich


Book ID
107814642
Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
1001 KB
Volume
48
Category
Article
ISSN
0022-3697

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Calorimetric investigations of the low-s
✍ S.K. Kulshreshtha; R. Sasikala; E. König 📂 Article 📅 1986 🏛 Elsevier Science 🌐 English ⚖ 290 KB

Based on measurements of differential scanning calorimetry, the first-order character of the spin-state transition in Fe(bt),(NCS), is established (bt = 2,2'-bi-2-thiazoline). The transition arises at T, ' =180.9 K and T,l =171.2 K, and is characterized by AH = 9.55 kO.7 kJ mol-' and AS = 54.5 \*4 J