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An infrared spectroscopic study of the low-spin-high-spin transition in FexMn1-x(Phen)2(NCS)2: A composition-induced change in the order of the spin-state transition

✍ Scribed by Vijay Varma; J.R. Fernandes


Book ID
107734929
Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
261 KB
Volume
167
Category
Article
ISSN
0009-2614

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The transition temperature of [Fe@hen)z(NCS)z ] measured by susceptibility measurements in an applied tield of 1 T shifts by -0.11 f 0.04 K when the field is increased to 55 T. This shift is predicted on the basis of the known magnetic susceptibility and specific heat data.