## Abstract The X‐ray structures of the novel spin crossover complex [Fe(pmea)(NCS)~2~] with pmea = (bis[(2‐pyridyl)methyl]‐2‐(2‐pyridyl)ethylamin) were determined in its low‐spin (singlet, LS) and high‐spin state (quintet, HS) and compared with the optimized geometries produced by BP86 calculation
✦ LIBER ✦
An investigation of the first-order spin-state transition in Fe(Phen)2(NCS)2 EXAFS and infrared spectroscopy
✍ Scribed by G. Sankar; John Meurig Thomas; Vijay Varma; G.U. Kulkarni; C.N.R. Rao
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 436 KB
- Volume
- 251
- Category
- Article
- ISSN
- 0009-2614
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Deuteration of the secondary amine functions of 4,7,10))] has been performed in order to investigate the H/D isotope effect on the intermolecular hydrogen bond network responsible for the propagation of the two-step spin-state transition along the linear chains of this unique material. M/~ssbauer sp