Electron spin resonance and Moessbauer study of the high-spin-low-spin transition in [Fe(phen)2(NCS)2] and [Fe(pic)3]Cl2.EtOH
โ Scribed by Rao, P. Sambasiva.; Reuveni, Amikam.; McGarvey, Bruce R.; Ganguli, Prabuddha.; Guetlich, Philipp.
- Book ID
- 125991116
- Publisher
- American Chemical Society
- Year
- 1981
- Tongue
- English
- Weight
- 475 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0020-1669
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๐ SIMILAR VOLUMES
Tne wsta! structure of the spin crossover complex [re(l-pic)l] CIZ -EtOH in its high spin stare (798. 150 K) and ION skin smtc (90 6) has been determined. The cry~ak are monoclinic. PZl/c \xith Z=4 in. the two spin states. Pronounced clung= in tire Fe-X bond distance (Z-I% A for high spin. 2.013 X f
The transition temperature of [Fe@hen)z(NCS)z ] measured by susceptibility measurements in an applied tield of 1 T shifts by -0.11 f 0.04 K when the field is increased to 55 T. This shift is predicted on the basis of the known magnetic susceptibility and specific heat data.